Molecular stereochemistry is a fundamental aspect of all areas of
chemistry. It is especially important in inorganic chemistry where the
coordination numbers are variable and occasionally quite high. The
present book evolved naturally from a series of articles written by
Professor Kepert for Progre88 in Inorganic Ohemi8try, elucida- ting
aspects of the stereochemistry of inorganic compounds of co- ordination
numbers 4-12. In the present volume, Professor Kepert has added new
sections and synthesized these individual chapters into a unified
treatment, updating his references when necessary to the most recent
contributions in the literature, and inter- weaving the various themes
as deemed appropriate. The result is a major contribution, describing
the stereochemistry of coordi- nation compounds having both unidentate
and multidentate ligands. The viability of the repulsion approach to
stereochemistry is tested to the limit in this treatise and shown to be
an extremely good way of rationalizing a diverse body of data.