The enzymatic polymerization of phenolic compounds has been generating
interest in several fields such as food, cosmetics, and pharmaceuticals.
These compounds are employed for their antioxidant properties; however,
their use is limited by their low solubility and thermal stability.
Polymerization can improve their solubility and their thermal stability
though and create new properties which are dependent on the molecular
mass and the structure of polymers. The reaction yield, the
polydispersity, the molecular mass, the structure and the properties of
synthesized polymers can be controlled by the mode of control of the
reaction and by the reaction conditions.
Enzymatic polymerization of phenolic compounds by oxidoreductases
analyze the processes used and the key factors (temperature, solvent,
origin of the enzyme, structure of the substrate, reactor design, ...)
which control the polymerization of phenolic species by these
oxidoreductase enzymes in order to obtain polymers with desired
characteristics and properties.