This book is the completely revised and extended version of the German
edition "Einfiihrung in die Elektrochemie fester Stoffe" which appeared
in 1973. Since then, the subject of the electro- chemistry of solids has
developed further and a large number of new solid electrolytes have been
discovered. With the help of solid electrolytes, i. e. solid ionic
conductors, galvanic cells are constantly being built for thermodynamic
or kinetic investigations and for technical applications. Though the
book takes these new develop- ments into consideration, its main aim is
to provide an introduction to the electrochemistry of solids,
emphasizing the principles of the subject but not attempting to present
a complete account of the existing literature. The latter can be found
in handbooks and specialists' reports of conferences in this field;
these are referred to in the text. This book is written for scientists
and graduate stu- dents who require an approach that will familiarize
them with this field. It is assumed that the reader will be acquainted
with the fundamentals of physical chemistry. The various chapters have
been written so that most of them can be read independently of each
other. Parts which may be omitted during a first reading are printed in
small type. Of vital importance for the publication of this English
edition have been the comments, suggestions and the help of colleagues
and co-workers. I would particularly like to express my thanks to Dr.
Holzapfel, Dl'. Lohmar, Professor Mitchell, Dr.