This book presents an account of the course "Disordered Solids:
Structures and Processes" held in Erice, Italy, from June 15 to 29,
1987. This meeting was organized by the International School of Atomic
and Molecular Spectroscopy of the "Ettore Majorana" Centre for
Scientific Culture. The objective of this course was to present the
advances in physical modelling, mathematical formalism and experimental
techniques relevant to the interpretation of the structures of
disordered solids and of the physical processes occurring therein.
Traditional solid-state physics treats solids as perfect crystals and
takes great advantage of their symmetry, by means of such mathematical
formalisms as the reciprocal lattice, the Brillouin zone, and the
powerful tools of group theory. Even if in reality no solid is a perfect
crystal, this theoretical approach has been of great usefulness in
describing solids: deviations from perfect order have been treated as
perturbations of the ideal model. A new situation arises with truly
disordered solids where any vestige of long range order has disappeared.
The basic problem is that of describing these systems and gaining a
scientific understanding of their physical properties without the
mathematical formalism of traditional solid- state physics. While some
of the old approaches may occasionally remain valid (e. g. chemical
bonding approach for amorphous solids), the old ways will not do.
Disorder is not a perturbation: with disorder, something basically new
may be expected to appear.